Hybrid, elastomeric hydrogels crosslinked by multifunctional block copolymer micelles
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Updated: Jun 4, 2026

Microwave-assisted Functionalization of Poly(ethylene glycol) and On-resin Peptides for Use in Chain Polymerizations and Hydrogel Formation
Published on: October 29, 2013
Longxi Xiao1, Chao Liu, Jiahua Zhu
1Department of Materials Science and Engineering, Delaware Biotechnology Institute, University of Delaware, Newark DE 19716, USA.
Abstract:
Amphiphlic block copolymers consisting of hydrophilic, poly(acrylic acid) randomly decorated with acrylate groups and hydrophobic, rubbery poly(n-butyl acrylate) self-assembled into well-defined micelles with an average diameter of ~21 nm. Radical polymerization of acrylamide in the presence of the crosslinkable micelles gave rise to hybrid, elastomeric hydrogels whose mechancial properties can be readily tuned by varying the BCM concentration.
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