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Manipulating coupling between a single semiconductor quantum dot and single gold nanoparticle.

Daniel Ratchford1, Farbod Shafiei, Suenne Kim

  • 1Department of Physics, University of Texas at Austin, Austin, Texas 78712, United States.

Nano Letters
|February 2, 2011
PubMed
Summary
This summary is machine-generated.

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We created hybrid nanostructures by placing gold nanoparticles near quantum dots. This significantly shortened the quantum dot’s light emission lifetime and eliminated blinking by enabling efficient energy transfer.

Area of Science:

  • Nanotechnology
  • Materials Science
  • Quantum Optics

Background:

  • Quantum dots (QDs) exhibit unique photoluminescence properties.
  • Controlling QD emission through external factors is crucial for applications.
  • Hybrid nanostructures offer tunable optical properties.

Purpose of the Study:

  • To construct and investigate a hybrid nanostructure comprising a single gold (Au) nanoparticle and a cadmium selenide/zinc sulfide (CdSe/ZnS) quantum dot.
  • To systematically vary the coupling between the Au nanoparticle and QD.
  • To analyze the impact on QD photoluminescence lifetime and blinking behavior.

Main Methods:

  • Atomic force microscopy (AFM) nanomanipulation for precise positioning of a single Au nanoparticle relative to a CdSe/ZnS QD.

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Nanofabrication of Gate-defined GaAs/AlGaAs Lateral Quantum Dots
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Nanofabrication of Gate-defined GaAs/AlGaAs Lateral Quantum Dots

Published on: November 1, 2013

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Last Updated: Jun 4, 2026

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Synthesis, Characterization, and Functionalization of Hybrid Au/CdS and Au/ZnS Core/Shell Nanoparticles
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15:47

Nanofabrication of Gate-defined GaAs/AlGaAs Lateral Quantum Dots

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  • Systematic and reversible variation of the interparticle coupling.
  • Measurement of photoluminescence lifetime and blinking of the QD before and after nanostructure assembly.
  • Main Results:

    • Construction of a hybrid nanostructure with controllable geometry.
    • Significant reduction in QD photoluminescence lifetime, from ~30 ns to below 1 ns in some cases.
    • Complete suppression of QD blinking due to dominant nonradiative energy transfer to the Au nanoparticle.
    • Observed changes in lifetime and intensity are accurately predicted by analytical models.

    Conclusions:

    • Nonradiative energy transfer from CdSe/ZnS QDs to Au nanoparticles can be effectively controlled by varying nanostructure geometry.
    • This energy transfer mechanism dramatically alters QD photoluminescence dynamics, reducing lifetime and eliminating blinking.
    • The findings provide a pathway for designing advanced nanomaterials with tailored optical properties.