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Updated: Jun 4, 2026

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
Published on: September 5, 2018
Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(II) frameworks
Man-Sheng Chen1, Min Chen, Satoshi Takamizawa
1Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, China.
Abstract:
A unique 4-fold interpenetrated (10,3)-b copper(II) framework exhibits reversible dehydration and rehydration in a single-crystal-to-single-crystal (SC-SC) process, and the dehydrated material can encapsulate CH(3)OH molecules, again in a SC-SC fashion, and shows selective adsorption of H(2) and CO(2) over N(2).
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