Effects of solvency and interfacial nanobubbles on surface forces and bubble attachment at solid surfaces
Xuehua Zhang1, Ashish Kumar, Peter J Scales
1Particulate Fluids Processing Centre, Department of Chemical and Biomolecular Engineering, University of Melbourne , VIC 3010, Australia.
Abstract:
The forces between a carbon sphere and highly ordered pyrolytic graphite (HOPG) surface were measured in ethanol aqueous solutions. A long-range attractive interaction was observed in ethanol aqueous solutions with less than 60% ethanol on a volume basis. The magnitude and the range of the attractive interaction decreased with an increase in ethanol concentration in solution. An air bubble was found to attach to the HOPG surface in solutions with an ethanol concentration less than 20 vol %. The presence of nanobubbles at the HOPG surface, made possible through a surface washing process and confirmed through in situ imaging, extended the range of both the long-range attraction and the bubble attachment regime to ethanol concentrations 60-80 vol %. The shear yield stress of suspensions of carbon black in ethanol-aqueous solutions was used as an indicator of the presence of a net attractive interaction between particles. The yield stress was observed to increase rapidly for ethanol concentrations less than 60 vol %. Contact angle analysis for ethanol-aqueous solutions in air showed that an angle of greater than 40° was required to induce a long-range attraction. Modeling indicated that the range and form of the interaction was consistent with a capillary cavitation force. The data clearly shows that surface nanobubbles are not critical to the development of a long-range attractive force, bubble pickup on surfaces, or enhanced suspension rheology, but that their presence greatly aids these processes.
Related Concept Videos
Surface Tension of Fluid
Surface tension varies with...
Surface Tension and Surface Energy
Consider a beaker filled with liquid. The bulk molecules in the liquid experience equal attractive forces on all sides with the surrounding molecules. However, the surface molecules experience a net attractive force downward due to the bulk molecules. The surface of the liquid behaves like a stretched membrane,...
Surface Tension, Capillary Action, and Viscosity
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
Surface Tension
Excess Pressure Inside a Drop and a Bubble
Contact Angle
The adhesive force is the molecular force between molecules of different materials, that is, between the molecules of the solid and the liquid. The cohesive force...


