Expeditious construction of a carbobicyclic skeleton via sp3-C-H functionalization: hydride shift from an aliphatic
Keiji Mori1, Shosaku Sueoka, Takahiko Akiyama
1Department of Chemistry, Faculty of Science, Gakushuin University, Toshima-ku, Tokyo, Japan.
Abstract:
Described herein is the first example of an aliphatic, nonbenzylic hydride shift/cyclization sequence that contains two types of novel sp(3)-C-H functionalization: (1) construction of a tetraline skeleton via [1,5]-hydride shift/cyclization and (2) [1,6]-hydride shift/cyclization to form a five-membered ring (indane derivatives).
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