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Updated: Jun 4, 2026
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Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes
Published on: August 16, 2018
The first ionothermal synthesis of a 3D ferroelectric metal-organic framework with colossal dielectric constant
Wen-Juan Ji1, Quan-Guo Zhai, Shu-Ni Li
1Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi Normal University, Xi' an, Shaanxi, 710062, P. R. China.
Chemical Communications (Cambridge, England)
|February 16, 2011
Abstract:
A novel 3D (4,6)-connected topological architecture, obtained under ionothermal conditions by using 1-ethyl-3-methyl imidazolium bromide ([EMI]Br) as solvent and structure-directing agent, presents a non-centrosymmetric polar packing arrangement showing an interesting ferroelectric property.
