CO2 selectivity of a 1D microporous adenine-based metal-organic framework synthesised in water
Kyriakos C Stylianou1, John E Warren, Samantha Y Chong
1Department of Chemistry, University of Liverpool, Crown Str., Liverpool L69 7ZD, UK.
Chemical Communications (Cambridge, England)
|February 19, 2011
Abstract:
The coordination of adenine to Ni(2+) forms a dimer unit which can be linked by 3,5-pyrazoledicarboxylic acid into chains which assemble under hydrothermal conditions via hydrogen bonding into a robust porous network. The material displays selectivity for CO(2) over CH(4) and an isosteric heat which increases with guest loading.
