Related Experiment Video
Updated: Jun 4, 2026

Synthesis, Characterization, and Functionalization of Hybrid Au/CdS and Au/ZnS Core/Shell Nanoparticles
Published on: March 2, 2016
Tunable hybridization in metal nanoshell chains
1Department of Physics, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, People's Republic of China.
Abstract:
We have studied the coupled surface plasmon (SP) modes in periodic metal nanoshell chains by including long range electromagnetic interactions. The eigen-decomposition method is used to analyze the dispersion and dissipation of the SP modes. The resulting band structure can be understood as a hybridization between a hole band and a particle band with a structurally tunable band gap in the middle of the first Brillouin zone. The mode quality, which is defined as the imaginary part of the generalized polarizability, increases as the shell thickness decreases. This indicates a larger energy loss and an increasing coupling between the bands. Through the manipulation of the band structures, the propagation of the coupled SP modes in the nanoshell chain can be controlled.
Related Concept Videos
Valence Bond Theory
Hybridization of Atomic Orbitals II
Hybridization of Atomic Orbitals I
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Biasing of Metal-Semiconductor Junctions
In Schottky junctions, where the semiconductor is n-type, applying a positive voltage to the metal relative to the semiconductor reduces its Fermi...
¹H NMR: Long-Range Coupling
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene π orbitals.
