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Step-wise synthesis of inorganic-organic hybrid based on γ-octamolybdate-based tectons
Hong-Ying Zang1, Ya-Qian Lan, Shun-Li Li
1Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, People's Republic of China.
Abstract:
With the bottom-up design principle, we use metal-ions to bridge the predesigned tectons (1 [(H(2)L(1))(2)(Mo(8)O(26))]·4H(2)O and 3 [(H(2)L(2))(L(2))(0.5)(Mo(8)O(26))(0.5)]·H(2)O) so that two higher dimensional γ-octamolybdate based inorganic-organic hybrid compounds 2 [Cu(I)(2)(L(1))(3)(Mo(8)O(26))(0.5)] and 4 [Ni(L(2))(2)(HL(2))(2)(Mo(8)O(26))]·4H(2)O are successfully obtained.

