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Bonding characters of Al-containing bulk metallic glasses studied by 27Al NMR

X K Xi¹, M T Sandor, H J Wang

¹Department of Physics and Astronomy, University of North Carolina, Chapel Hill, NC 27599-3255, USA.

Journal of Physics. Condensed Matter : an Institute of Physics Journal

|March 2, 2011

Abstract:

We report very small (27)Al metallic shifts in a series of Cu-Zr-Al bulk metallic glasses. This observation and the Korringa type of spin-lattice relaxation behavior suggest that s-character wavefunctions weakly participate in bonding and opens the possibility of enhanced covalency (pd hybridization) with increasing Al concentration, in good agreement with elastic constants and hardness measurements. Moreover, ab initio calculations show that this bonding character originates from the strong Al 3p band and Zr 4d band hybridization since their atomic energy levels are closer to each other while the Al 3s band is localized far below the Fermi level. This study might provide a chemical view for understanding flow and fracture mechanisms of these bulk glass-forming alloys.

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