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Updated: Jun 4, 2026

Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Raman spectroscopic study of the rare-earth fullerides Eu6-xSrxC60
J Arvanitidis1, D Christofilos, G A Kourouklis
1Department of Applied Sciences, Technological Educational Institute of Thessaloniki, 57400, Sindos, Greece. jarvan@eng.auth.gr
Abstract:
We present Raman spectroscopic studies of the isostructural and isoelectronic Eu(6-x)Sr(x)C(60) (x = 0, 3, 5, 6) and Ba(6)C(60) compounds. The Raman spectra of the Eu-based fullerides show dramatic changes compared to the pure alkaline-earth systems, including significant broadening, splitting and frequency shifts of the fivefold degenerate H(g) intramolecular modes of C(60). Moreover, the A(g)(2) mode exhibits an even larger downshift and a remarkable broadening. These findings are consistent with distortions of the C(60) molecular cages and a considerable electron-phonon coupling strength-strongly enhanced in the Eu containing systems-originating from the strong orbital hybridization between the metal atom and the C(60) molecule.
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