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Electrospinning of Photocatalytic Electrodes for Dye-sensitized Solar Cells
Published on: June 28, 2017
Dye-sensitized solar cells based on TiO2-B nanobelt/TiO2 nanoparticle sandwich-type photoelectrodes with controllable
Youzhen Dong1, Kai Pan, Guohui Tian
1Key Laboratory of Functional Inorganic Material Chemistry (Heilongjiang University), Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.
Abstract:
The TiO(2)-B nanobelt (NB)/TiO(2) nanoparticle (NP) sandwich-type structure photoelectrode, with controllable nanobelt length, has been used to fabricate high-efficiency dye-sensitized solar cells (DSSCs), which combine the advantages of the rapid electron transport in TiO(2)-B NBs and the high surface area of TiO(2) NPs. The results indicate that the sandwich-type photoelectrode achieves higher photoelectrical conversion efficiency when compared with the TiO(2) nanoparticulate electrode. Increasing the length of TiO(2)-B NBs has been demonstrated to improve the photoelectric conversion efficiency (η). DSSCs with the longest (10 μm) TiO(2)-B NBs yield the highest η of 7.94%. The interfacial electron transport of DSSCs with different lengths of TiO(2)-B NBs has been quantitatively investigated using the photovoltage transient and the electrochemical impedance spectra, which demonstrates that the DSSCs with longest TiO(2)-B NBs display the highest electron collection efficiency and the fastest interfacial electron transfer.

