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Updated: Jun 3, 2026

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Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
A permanently porous van der Waals solid by using phosphonate monoester linkers in a metal organic framework
Simon S Iremonger1, Junmei Liang, Ramanathan Vaidhyanathan
1Department of Chemistry, University of Calgary, Canada.
Abstract:
A bis(phosphonatemonoester) is employed as a linker in a Zn(II) metal organic framework. The complex is a layered structure pillared only by vdW interactions between alkyl groups. Nonetheless, permanent pores are formed as confirmed by PXRD and gas sorption analysis.
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