Related Experiment Video
Updated: Jun 3, 2026
Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Phase coexistence in manganites: doping and structural dependence
G Alejandro1, M Otero-Leal, M Granada
1Centro Atómico Bariloche, 8400 San Carlos de Bariloche, Río Negro, Argentina. galejand@cab.cnea.gov.ar
Abstract:
We present a study on the phase coexistence (PC) of paramagnetic insulating (PM-I) and ferromagnetic metallic (FM-M) phases in the La(1- y)(Ca(1-x)Sr(x))(y)MnO(3) system with 0.23 ≤ y ≤ 0.45. The study was performed by means of magnetization and electron spin resonance (ESR) measurements. At high temperatures the ESR spectrum consists of a single symmetric PM line. At T(C), a FM asymmetric line is observed shifted to low fields. In a ΔT temperature range both lines are visible, defining a range of PC. For x = 0, we obtained ΔT as a function of the carrier concentration y, finding that the largest ΔT corresponds to y = 0.25. For this y value, the extreme compounds are orthorhombic and rhombohedral for x = 0 and 1, respectively. The rhombohedral to orthorhombic temperature transition (T(RO)) was determined as a function of x. We found that [Formula: see text] only if T(C) < T(RO). The PM-I/FM-M phase coexistence was only observed in the orthorhombic phase while seems to be incompatible with the more symmetric rhombohedral phase.
Related Concept Videos
03:02Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
02:42Valence Bond Theory
02:34Structural Isomerism
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can be...
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
01:31Ferromagnetism
01:29Imperfections in Crystal Structure: Non-Stoichiometric Defects