Anelastic loss behaviour of mobile microstructures in SrZr(1-x)Ti(x)O3 perovskites

Anelastic loss mechanisms associated with phase transitions in SrZr(1-x)Ti(x)O(3) perovskites (x = 0.375, 0.450, 0.550, 0.775) have been investigated by dynamic mechanical analysis between 128 and 723 K at frequencies of 0.1-50 Hz. Distinctive patterns of changes in the elastic moduli due to octahedral tilting transitions correlate closely with data for the shear modulus obtained previously by resonant ultrasound spectroscopy at high frequencies (∼0.5 MHz). The I4/mcm <--> Imma transition is first order and has a characteristic minimum in the shear modulus and Young's modulus. For x = 0.450 and 0.550, a dissipation peak occurs at the transition temperature, the maximum of which varies with frequency according to a power law relationship of the form tanδ = Af(n), with n≈ - 0.3. Debye-like dissipation peaks in the stability field of the Imma structure at x = 0.375 have a frequency and temperature dependence consistent with twin wall pinning by defects with an activation energy ∼ 184 kJ mol(-1). These results indicate that there is diversity of pinning and relaxation processes for transformation twin walls and interfaces in different perovskites with I4/mcm, Imma and Pnma structures.