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Updated: Jun 3, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
Published on: April 19, 2019
Isolable, gold carbonyl complexes supported by N-heterocyclic carbenes
Chandrakanta Dash1, Peter Kroll, Muhammed Yousufuddin
1Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, Texas 76019-0065, USA.
Abstract:
Cationic gold carbonyl complexes supported by N-heterocyclic carbene ligands, SIDipp and IDipp, have been synthesized. [(SIDipp)Au(CO)][SbF(6)] has a linear, two-coordinate gold center. [(SIDipp)Au(CO)][SbF(6)] and [(IDipp)Au(CO)][SbF(6)] display ̃ν(CO) values at 2197 and 2193 cm(-1), respectively. Computational studies on [(SIMe)Au(CO)](+) indicate the presence of a strong Au(I)-CO bond.
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