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Updated: Jun 3, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Infinite terbium(III) chains formed from a tetra-phosphorylated resorcinarene cavitand
Hani El Moll1, David Sémeril, Dominique Matt
1Laboratoire de Chimie Inorganique et Catalyse, Université de Strasbourg, Institut de Chimie de Strasbourg, UMR 7177 CNRS, 1, rue Blaise-Pascal, 67008, Strasbourg cedex, France.
Abstract:
Reaction of [Tb(III)(DMSO)(8)](CF(3)SO(3))(3) with a resorcinarene cavitand substituted by four -CH(2)P(O)Ph(2) pendant arms afforded an infinite 1D inorganic polymer, in which the consecutive resorcinarene units are linked through two terbium strands, this connection involves pairs of phosphoryl groups occupying adjacent positions of the resorcinarene units.
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