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Updated: Jun 3, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Hydrogen generation from formic acid decomposition by ruthenium carbonyl complexes. Tetraruthenium dodecacarbonyl
Miklos Czaun1, Alain Goeppert, Robert May
1Loker Hydrocarbon Research Institute, University Park Campus, University of Southern California, Los Angeles, CA 90089-1661, USA.
Abstract:
The present Minireview covers the formation and the structural characterization of noble metal carbonyl and hydrido carbonyl complexes, with particular emphasis on ruthenium complexes using formic acid as a carbonyl and hydride source. The catalytic activity of these organometallic compounds for the decarboxylation of formic acid, a potential hydrogen storage material, is also reviewed. In addition, the first preparation of [Ru(4)(CO)(12)H(4)] from RuCl(3) and formic acid as well as the catalytic activity of [Ru(4)(CO)(12)H(4)] for the decomposition of formic acid to hydrogen and carbon dioxide are presented.
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