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Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
06:55

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level

Published on: September 26, 2016

Polymer translocation induced by a bad solvent.

Christopher Lörscher1, Tapio Ala-Nissila, Aniket Bhattacharya

  • 1Department of Physics, University of Central Florida, Orlando, Florida 32816-2385, USA.

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|March 17, 2011
PubMed
Summary
This summary is machine-generated.

Polymer translocation through nanopores is accelerated by solvent asymmetry. A globule formed in a bad solvent near the pore enhances translocation speed, aligning with theoretical predictions.

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Area of Science:

  • Soft Matter Physics
  • Polymer Physics
  • Nanotechnology

Background:

  • Polymer translocation through nanopores is crucial for biological processes and nanotechnology.
  • Understanding translocation dynamics is key to controlling polymer behavior at the nanoscale.

Purpose of the Study:

  • Investigate polymer translocation dynamics under solvent asymmetry using 3D Langevin dynamics.
  • Analyze the effect of solvent interaction strength on translocation time and chain conformation.

Main Methods:

  • Simulated polymer chains in three dimensions using Langevin dynamics.
  • Created solvent asymmetry by placing cis and trans compartments in different solvents.
  • Varied the interaction strength (ɛ/k(B)T) for the bad solvent.

Main Results:

  • Translocation time (τ) scales with solvent interaction strength as (τ)~(ɛ/k(B)T)(-1) and chain length as (τ)~N(1.1±0.05) for ɛ/k(B)T≥1.
  • The formation of a globule in the bad solvent near the pore accelerates translocation.
  • Observed faster translocation compared to driven translocation due to efficient absorption of polymer segments.

Conclusions:

  • Solvent asymmetry significantly impacts polymer translocation dynamics through nanopores.
  • The formation of a collapsed globule in a poor solvent enhances translocation efficiency.
  • Simulation results validate theoretical predictions for driven polymer translocation.