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Density functional for hard hyperspheres from a tensorial-diagrammatic series
Gavin Leithall1, Matthias Schmidt
1H. H. Wills Physics Laboratory, University of Bristol, Royal Fort, Tyndall Avenue, Bristol BS8 1TL, United Kingdom.
Abstract:
We represent the free energy functional by a diagrammatic series with tensorial coefficients indexed by powers of the length scale. For hard cores, we obtain Percus's exact functional in one dimension and the Kierlik-Rosinberg form of fundamental measures theory in three dimensions. In five dimensions, the functional describes bulk fluids better than does the Percus-Yevick theory. At planar walls, density profiles oscillate with smaller periods than in lower dimensions. Our findings open up avenues for treating both more general high-dimensional systems and three-dimensional mixtures via dimensional reduction.
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