Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Radicals: Electronic Structure and Geometry01:07

Radicals: Electronic Structure and Geometry

This lesson delves into the geometry of a radical, which is influenced by the electronic structure of the molecule. The principle is similar to that of a lone pair, where the unpaired electron influences the geometry at the radical center.
Accordingly, the structure of a trivalent radical lies between the geometries of carbocations and carbanions. An sp2-hybridized carbocation is trigonal planar, while an sp3-hybridized carbanion is trigonal pyramidal. Here, the difference in geometry is...
Debye–Huckel–Onsager Conductance Equation01:28

Debye–Huckel–Onsager Conductance Equation

The Debye-Hückel-Onsager equation is a cornerstone of physical chemistry, providing a method to determine the molar conductance (Λm) and molar conductance at infinite dilution (Λ°m) for uni-univalent electrolytes.Uni-univalent electrolytes are electrolytes that dissociate in solution to produce one cation with a +1 charge and one anion with a –1 charge per formula unit.This equation addresses two crucial phenomena: the asymmetry effect and the electrophoretic effect. According to this equation,...
π Electron Effects on Chemical Shift: Overview01:27

π Electron Effects on Chemical Shift: Overview

An applied magnetic field causes loosely bound π-electrons in organic molecules to circulate, producing a local or induced diamagnetic field over a large spatial volume. As the molecules tumble in solution, the field generated by π-electrons in spherical substituents results in a zero net field. However, the net field generated by π-electrons in non-spherical substituents is not zero. The effect of this induced field depends on the orientation of the molecule with respect to B0, resulting in...
Molecular Orbital Theory II03:51

Molecular Orbital Theory II

Molecular Orbital Energy Diagrams
Crystallographic Point Groups01:29

Crystallographic Point Groups

Crystallographic point groups represent the various symmetry operations that can occur within crystals. They are unique in that at least one point will always remain unchanged during these actions. For instance, consider the triclinic system. This system, devoid of any axis or plane of symmetry, aligns with the C1 and Ci point groups.where Cᵢ is characterized solely by a center of inversion.Contrastingly, the monoclinic system introduces an element of symmetry. This system with one plane and...
Trends in Lattice Energy: Ion Size and Charge02:54

Trends in Lattice Energy: Ion Size and Charge

An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Corneal nerve axonal characteristics in chronic whiplash-associated disorder: An in vivo confocal microscopy case series.

Contact lens & anterior eye : the journal of the British Contact Lens Association·2026
Same author

Diagnostic accuracy of self-collected anterior nasal swabs for SARS-CoV-2 RT-PCR testing.

Microbiology spectrum·2025
Same author

Discordant dry eye disease and chronic pain: A systematic review and meta-analysis.

Contact lens & anterior eye : the journal of the British Contact Lens Association·2024
Same author

Heparin-mediated PCR interference in SARS-CoV-2 assays and subsequent reversal with heparinase I.

Journal of virological methods·2024
Same author

Influences on the dietary intakes of preschool children: a systematic scoping review.

The international journal of behavioral nutrition and physical activity·2022
Same author

Validation of the Kinetik Blood Pressure Monitor-Series 1 for use in adults at home and in clinical settings, according to the 2002 European Society of Hypertension International Protocol on the validation of blood pressure devices.

Journal of human hypertension·2020

Related Experiment Video

Updated: Jun 3, 2026

Computation of Atmospheric Concentrations of Molecular Clusters from ab initio Thermochemistry
12:11

Computation of Atmospheric Concentrations of Molecular Clusters from ab initio Thermochemistry

Published on: April 8, 2020

A new renormalization group approach for systems with strong electron correlation.

K Edwards1, A C Hewson

  • 1Department of Mathematics, Imperial College, London SW7 2AZ, UK.

Journal of Physics. Condensed Matter : an Institute of Physics Journal
|March 17, 2011
PubMed
Summary

Researchers show how to study electron correlation effects in metals by suppressing spin fluctuations with a magnetic field. This method allows calculation of the Kondo temperature (T(K)) using renormalized perturbation theory, offering a new approach to understanding heavy fermion materials.

More Related Videos

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
08:04

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids

Published on: May 27, 2020

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
08:55

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses

Published on: June 7, 2018

Related Experiment Videos

Last Updated: Jun 3, 2026

Computation of Atmospheric Concentrations of Molecular Clusters from ab initio Thermochemistry
12:11

Computation of Atmospheric Concentrations of Molecular Clusters from ab initio Thermochemistry

Published on: April 8, 2020

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
08:04

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids

Published on: May 27, 2020

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
08:55

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses

Published on: June 7, 2018

Area of Science:

  • Condensed matter physics
  • Quantum mechanics
  • Materials science

Background:

  • Anomalous low-energy behavior in strongly correlated metals, like heavy fermion materials, is linked to electron scattering by spin fluctuations.
  • This scattering causes the Kondo effect, establishing a low-energy scale known as the Kondo temperature (T(K)).
  • Accessing these low energy scales typically requires non-perturbative methods due to strong local electron interactions.

Purpose of the Study:

  • To present a novel method for calculating low-energy properties in strongly correlated systems.
  • To circumvent the need for non-perturbative approaches by utilizing magnetic fields.
  • To demonstrate the viability of this approach for the single impurity Anderson model.

Main Methods:

  • Suppressing spin fluctuations by applying a large magnetic field.
  • Calculating field-dependent renormalized parameters using standard perturbation theory.
  • Employing renormalized perturbation theory iteratively to progressively reduce the magnetic field strength down to zero.

Main Results:

  • Demonstrated a method to calculate renormalized parameters as a function of magnetic field.
  • Successfully applied the approach to the single impurity Anderson model.
  • Obtained results for renormalized parameters that can be validated against established methods like numerical renormalization group and Bethe ansatz.

Conclusions:

  • The proposed method offers a viable alternative to non-perturbative calculations for studying low-energy phenomena in strongly correlated systems.
  • Magnetic field-induced suppression of spin fluctuations provides a pathway to analyze the Kondo effect and related phenomena.
  • This work opens new avenues for theoretical investigations of heavy fermion materials and other correlated electron systems.