Suppression of itinerant ferromagnetism and a spin-glass-like state in Zn substituted La0.67Ca0.33MnO3

We examine the magneto-transport, static and dynamic magnetic responses of the single phase glassy insulating compound La(0.67)Ca(0.33)Mn(1-x)Zn(x)O(3) (x = 0.10). This compound undergoes a field induced metal-insulator transition and exhibits colossal magnetoresistance for H ≥ 2 T. Many experimental features, such as a frequency dependent cusp in the in-phase component of linear ac susceptibility at a temperature T'(f), a broad maximum (at T(a)) in the ZFC cooled thermo-magnetization close to T'(f), large thermo-magnetic irreversibility below T(a), non-saturation of magnetization at 5 K even under 12 T with a characteristic S shape in the virgin curve, monotonic increase of the coercivity at low fields under ZFC condition as one approaches the T'(f), logarithmic relaxation of thermo-magnetization and ageing effects below T(a) and a characteristic maximum in the magnetic viscosity below the spin-glass transition temperature (T(g)) indicate a spin-glass-like state at low temperatures. This is further substantiated by the absence of second order non-linear ac susceptibility, a characteristic negative maximum at T(g) in third order non-linear ac susceptibility (χ'(3)), the critical divergence of χ'(3) as a function of temperature and ac probe field and an unusually large linear term in the low temperature specific heat.