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Tunable metal-enhanced fluorescence by stimuli-responsive polyelectrolyte interlayer films.

Ning Ma1, Fu Tang, Xiaoyu Wang

  • 1School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China.

Macromolecular Rapid Communications
|March 26, 2011
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We demonstrate tunable metal-enhanced fluorescence (MEF) using silver nanostructures and porphyrin molecules. By adjusting an interlayer, we controlled the distance, enhancing fluorescence up to 25-fold.

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Area of Science:

  • Nanotechnology
  • Materials Science
  • Spectroscopy

Background:

  • Metal-enhanced fluorescence (MEF) offers a powerful route to amplify weak molecular signals.
  • Silver (Ag) nanostructures exhibit excellent plasmonic properties suitable for MEF applications.
  • Controlling the distance between fluorophores and nanostructures is crucial for optimizing MEF.

Purpose of the Study:

  • To investigate the tunable MEF of silver nanostructures with porphyrin molecules.
  • To explore the use of stimulus-responsive polymer multilayers for distance control in MEF.
  • To achieve controlled modulation of MEF intensity through environmental stimuli.

Main Methods:

  • Fabrication of highly dendritic silver (Ag) nanostructures.
  • Incorporation of porphyrin molecules (Por⁴⁻) as fluorophores.
  • Assembly of a stimulus-responsive poly(acrylic acid)/poly(diallyldimethylammonium chloride) (PAA/PDDA) multilayer film as an interlayer.
  • Tuning the distance between Por⁴⁻ and Ag nanostructures by varying ionic strength and pH.

Main Results:

  • Achieved a significant enhancement of porphyrin fluorescence by up to 25 times using Ag nanostructures.
  • Demonstrated controlled tuning of MEF intensity by adjusting the interlayer thickness via ionic strength and pH.
  • Confirmed the distance-dependent nature of MEF effects in the composite system.

Conclusions:

  • The developed system allows for tunable MEF through controlled manipulation of fluorophore-nanostructure distance.
  • Stimulus-responsive polymer multilayers provide an effective platform for dynamic MEF modulation.
  • This approach holds promise for applications requiring sensitive and controllable fluorescence enhancement.