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Updated: Jun 3, 2026

Assessment of Boron Doped Diamond Electrode Quality and Application to In Situ Modification of Local pH by Water Electrolysis
Published on: January 6, 2016
Highly stable redox-active molecular layers by covalent grafting to conductive diamond
Rose E Ruther1, Matthew L Rigsby, James B Gerken
1Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, Wisconsin 53706, United States.
Abstract:
We demonstrate a modular "click"-based functionalization scheme that allows inexpensive conductive diamond samples to serve as an ultrastable platform for surface-tethered electrochemically active molecules stable out to ∼1.3 V vs Ag/AgCl. We have cycled surface-tethered Ru(tpy)(2) to this potential more than 1 million times with little or no degradation in propylene carbonate and only slightly reduced stability in water and acetonitrile.
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