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Updated: Jun 3, 2026
Synthesis of Esters Via a Greener Steglich Esterification in Acetonitrile
Published on: October 30, 2018
Glycerol and derived solvents: new sustainable reaction media for organic synthesis
Alba E Díaz-Álvarez1, Javier Francos, Beatriz Lastra-Barreira
1Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica Enrique Moles (Unidad Asociada al CSIC), Universidad de Oviedo, Julián Clavería 8, 33006 Oviedo, Spain.
Abstract:
The rapid growth of the biodiesel industry has led to a large surplus of its major byproduct, i.e. glycerol, for which new applications need to be found. Research efforts in this area have focused mainly on the development of processes for converting glycerol into value-added chemicals and its reforming for hydrogen production, but recently, in line with the increasing interest in the use of alternative greener solvents, an innovative way to revalorize glycerol and some of its derivatives has seen the light, i.e. their use as environmentally friendly reaction media for synthetic organic chemistry. The aim of the present Feature Article is to provide a comprehensive overview on the developments reached in this field.
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