Exploring the uranyl organometallic chemistry: from single to double uranium-carbon bonds
Jean-Christophe Tourneux1, Jean-Claude Berthet, Thibault Cantat
1CEA, IRAMIS, SIS2M, CNRS UMR 3299, CEA/Saclay, 91191 Gif-sur-Yvette, France.
Journal of the American Chemical Society
|April 2, 2011
Abstract:
Uranyl organometallic complexes featuring uranium(VI)-carbon single and double bonds have been obtained from uranyl UO(2)X(2) precursors by avoiding reduction of the metal center. X-ray diffraction and density functional theory analyses of these complexes showed that the U-C and U=C bonds are polarized toward the nucleophilic carbon.
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