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Batatins III-VI, glycolipid ester-type dimers from Ipomoea batatas

Daniel Rosas-Ramírez1, Edgar Escalante-Sánchez, Rogelio Pereda-Miranda

  • 1Departamento de Farmacia, Facultad de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Mexico, DF, Mexico.

Phytochemistry
|April 2, 2011
PubMed

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Preparation of Diols and Pinacol Rearrangement01:57

Preparation of Diols and Pinacol Rearrangement

Compounds bearing two hydroxyl groups are known as diols. When the hydroxyl groups are located on adjacent carbon atoms, the diols are called vicinal diols or glycols. Under acidic conditions, vicinal diols undergo a specific reaction called pinacol rearrangement.
The reaction begins with transferring a proton from the acid catalyst to one of the hydroxyl groups, producing an oxonium ion.