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Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
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Accurate quantum-chemical description of gold complexes with pyridine and its derivatives

Doreen Mollenhauer1, Johannes Floss, Hans-Ulrich Reissig

  • 1Institute of Chemistry and Biochemistry-Physical and Theoretical Chemistry, Freie Universität Berlin, Takustra 3, 14195 Berlin, Germany. cmodo@chemie.fu-berlin.de

Journal of Computational Chemistry
|April 7, 2011
PubMed

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Heterocyclic amines, where the N atom is a part of an alicyclic system, are similar in basicity to alkylamines. Interestingly, the heterocyclic amine having a nitrogen atom as part of an aromatic ring has much less basicity than its corresponding alicyclic counterpart. For this reason, as presented in Figure 1, piperidine (pKb = 2.8) is significantly more basic than pyridine (pKb = 8.8).