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Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
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Monomer conversion in dual-cured core buildup materials.

N Kournetas1, I Tzoutzas, G Eliades

  • 1National and Kapodistrian University of Athens, Department of Operative Dentistry, Athens, Greece. nikos.kournetas@gmail.com

Operative Dentistry
|April 15, 2011
PubMed
Summary

Light-curing (LC) initiation improved dual-cured buildup restorative materials (DCB) conversion compared to self-curing (SC) mechanisms. However, dedicated SC and LC materials generally outperformed DCB, except for LuxaCore DC in LC mode.

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Area of Science:

  • Dental Materials Science
  • Polymer Chemistry
  • Restorative Dentistry

Background:

  • Dual-cured buildup restorative materials (DCB) combine self-curing (SC) and light-curing (LC) properties.
  • Understanding the curing efficiency of different mechanisms is crucial for material selection and clinical success.

Purpose of the Study:

  • To compare the curing efficiency of SC and LC mechanisms in DCB materials.
  • To evaluate the impact of polymerization mode on the conversion of C=C bonds in DCB.

Main Methods:

  • Four DCB materials were tested: Clearfil DC Core Automix (CD), Cosmecore DC (CM), LuxaCore DC (LX), and MultiCore DC Flow (MC).
  • Specimens were stored in dark, dry conditions for up to 60 minutes or light-cured immediately.
  • Remaining C=C bonds (%RDB) were quantified using ATR-FTIR spectroscopy.

Main Results:

  • Polymerization mode significantly affected DCB efficacy (p<0.0001).
  • Dedicated SC and LC control materials generally showed higher conversion than DCB materials.
  • LuxaCore DC (LX) and MultiCore DC Flow (MC) exhibited better SC conversion initially; CM maintained >60% RDB after 60 minutes.

Conclusions:

  • LC initiation enhanced C=C conversion in DCB compared to their native SC mechanisms.
  • Dedicated SC and LC materials generally outperformed DCB, with LX in LC mode being an exception.
  • Clinical performance may vary based on the material's specific curing characteristics.