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Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyl(tropone)iron
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Published on: August 12, 2019

Gold- and copper-catalyzed cycloisomerizations towards the synthesis of thujopsanone-like compounds

Charles Fehr1, Magali Vuagnoux, Andrea Buzas

  • 1Firmenich SA, Corporate R&D Division, P. O. Box 239, CH-1211 Geneva 8, Switzerland. charles.fehr@firmenich.com

Chemistry (Weinheim an Der Bergstrasse, Germany)
|April 20, 2011
PubMed

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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