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Updated: Jun 2, 2026

Measuring Dissolved Methane in Aquatic Ecosystems Using An Optical Spectroscopy Gas Analyzer
Published on: July 26, 2024
[Experimental study on Raman spectroscopy of alkane gases in simulated deep-sea extreme environments]
Jun Ma1, Ye-Fei Qu, Yang-Yu Huang
1College of Information Science and Engineering, Ocean University of China, Qingdao 266100, China. majun@ouc.edu.cn
Abstract:
In the present work, Raman spectra of alkane gases aqueous solution under simulated deep-sea hydrothermal environment were acquired by high temperature and high pressure deep-sea simulation experiment system. The variation laws of the Raman spectral features with various temperature and pressure were analyzed and mathematical model between them were established. The results show that for all Raman peaks of these alkane gases in aqueous solution the frequency is lower than gaseous state because of hydrogen bond; the variations of their Raman spectrum were not obvious as the pressure increased (< or = 40 MPa) in room temperature; and all peak positions move to lower wave number and their full width at half maximum (FWHM) increased along with changing temperature in the range of room temperature to 350 degrees C at 40 MPa pressure. The results provide an experimental basis for the in-situ detection of deep sea by Raman laser spectroscopy system in hydrothermal environment.
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