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A donor-functionalized, silyl-substituted pentadienyllithium: structural insight from experiment and theory

Sophia A Solomon1, F Matthias Bickelhaupt, Richard A Layfield

  • 1School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK M13 9PL.

Chemical Communications (Cambridge, England)
|April 27, 2011
PubMed
Summary

Researchers synthesized a novel silyl-substituted pentadienyllithium compound. Crystallography and spectroscopy revealed a partially localized negative charge on the pentadienyl group due to lithium cation interactions.

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