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Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
Published on: August 22, 2018
Butane-1,4-diaminium 2-(meth-oxy-carbon-yl)benzoate dihydrate
1Department of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, People's Republic of China.
Abstract:
In the title compound, C(4)H(14)N(2) (+)·2C(9)H(7)O(4) (-)·2H(2)O, the butane-1,4-diaminium cation lies on an inversion center. In the crystal, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the components into layers parallel to (100). Addtional stabilization within these layers is provided by weak inter-molecular C-H⋯O hydrogen bonds.
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