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4-Bromo-2-[(E)-(4-fluoro-phen-yl)imino-meth-yl]phenol.
Acta Crystallographica. Section E, Structure Reports Online
|April 28, 2011
Summary
The crystal structure of a novel brominated fluorinated organic compound reveals a near-planar conformation between its benzene rings. Intramolecular hydrogen bonds create specific ring structures within the molecule.
Area of Science:
- Crystallography
- Organic Chemistry
- Supramolecular Chemistry
Background:
- Understanding molecular conformation and intermolecular interactions is crucial in crystal engineering.
- The study of halogenated organic compounds provides insights into structure-property relationships.
Purpose of the Study:
- To elucidate the crystal structure and intermolecular interactions of the title compound, C(13)H(9)BrFNO.
- To investigate the conformational preferences and hydrogen bonding patterns in this novel organic molecule.
Main Methods:
- Single-crystal X-ray diffraction analysis was employed to determine the molecular structure.
- Analysis of the crystal structure included bond lengths, bond angles, and dihedral angles.
Main Results:
- The dihedral angle between the substituted benzene rings in C(13)H(9)BrFNO was found to be 9.00(11)°, indicating a nearly planar arrangement.
- Strong intramolecular O-H⋯N hydrogen bonds were identified, forming characteristic S(6) ring motifs.
Conclusions:
- The title compound exhibits a conformationally constrained structure due to significant intramolecular hydrogen bonding.
- The identified S(6) ring motifs are a key feature influencing the packing and properties of the crystal structure.
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