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Updated: Jun 2, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
cis-Dichloridotetra-kis-(trimethyl-phosphane-κP)ruthenium(II) benzene disolvate
1Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, People's Republic of China.
Abstract:
The title compound, cis-[RuCl(2)(C(3)H(9)P)(4)]·2C(6)H(6), contains a complex mol-ecule with a crystallographic mirror plane passing through the Ru(II) atom, the two cis-disposed Cl ligands and two P atoms of the two cis-disposed P(CH(3))(3) ligands. The Ru(II) atom adopts a distorted octa-hedral RuCl(2)P(4) coordination geometry with the two trans-disposed P atoms occupying the axial positions. The packing of the structure is accomplished through non-classical C-H⋯Cl hydrogen bonds between the benzene solvent mol-ecule and one of the Cl ligands.
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