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Updated: Jun 2, 2026

Thermochemical Studies of Ni(II) and Zn(II) Ternary Complexes Using Ion Mobility-Mass Spectrometry
Published on: June 8, 2022
Aqua-bis-(benzoato-κO)(1,10-phenanthroline-κN,N')zinc(II)
Ji-Zhong Liu1, Zhong Zhang, Zhan-Wang Shi
1Department of Chemistry, Guangxi University for Nationalities, Nanning 530006, People's Republic of China.
Abstract:
The Zn atom in the title compound, [Zn(C(7)H(5)O(2))(2)(C(12)H(8)N(2))(H(2)O)], is five-coordinate in a distorted trigonal-bipyramidal coordination environment involving two O atoms of two monodentate benzoates, two N atoms of a 1,10-phenanthroline mol-ecule and one O atom of a water mol-ecule. The axial positions are occupied by a carboxyl-ate O atom from the benzoate ligand and an N atom from the 1,10-phenanthroline ligand [N-Zn-O = 146.90 (7)°]. The water mol-ecule forms an intra-molecular O-H⋯O hydrogen bond; an inter-molecular O-H⋯O hydrogen bond gives rise to a dimer.
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