Dibromidobis[1-(2,4,6-trimethyl-phen-yl)-1,4,5,6-tetra-hydro-pyrimidine-κN]palladium(II)
Abstract:
In the title complex, [PdBr(2)(C(13)H(18)N(2))(2)], the Pd(II) atom is situated on an inversion center. The tetra-hydro-pyrimidine group of the N-(2,4,6-trimethyl-phen-yl)-1,4,5,6-tetra-hydro-pyrimidine ligand is twisted from the square (PdN(2)Br(2)) coordination plane with a C-N-Pd-Br torsion angle of 81.8 (4)°; this is different from the angle of 43.47 (14)°, reported in a closely related structure, dichloridobis(1-methyl-1,4,5,6-tetra-hydro-pyrimidine)-palladium(II).
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![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)