Related Experiment Video
Updated: Jun 2, 2026

Synthesis of a Water-soluble Metal–Organic Complex Array
Published on: October 8, 2016
Di-μ-methanolato-κO:O-bis[tri-chlorido(dimethyl-formamide-κO)tin(IV)]
Qijun Zhang1, Handong Yin, Daqi Wang
1College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.
Abstract:
The title compound, [Sn(2)(CH(3)O)(2)Cl(6)(C(3)H(7)NO)(2)], contains two hexa-coordinated Sn(IV) atoms symmetrically bridged by two deprotonated methanol ligands, with an inversion center in the middle of the planar Sn(2)O(2) ring. The other sites of the distorted octa-hedral coordination geometry of the Sn(IV) atom are occupied by three Cl atoms and one O atom from a dimethyl-formamide mol-ecule. The complex mol-ecules are connected by weak C-H⋯Cl hydrogen bonds into a two-dimensional supra-molecular network parallel to (10).
Related Concept Videos
Acidity and Basicity of Alcohols and Phenols
Preparation of Diols and Pinacol Rearrangement
The reaction begins with transferring a proton from the acid catalyst to one of the hydroxyl groups, producing an oxonium ion.
Properties of Organometallic Compounds
Multiple Halogenation of Methyl Ketones: Haloform Reaction
