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Updated: Jun 2, 2026

Facet-to-facet Linking of Shape-anisotropic Colloidal Cadmium Chalcogenide Nanostructures
Published on: August 10, 2017
Poly[dibromidobis[μ-1-(pyridin-4-ylmeth-yl)-1H-1,2,4-triazole-κN:N']cadmium]
Xiu-Zhi Xu1, Zhu-Lai Li, Wen-Jin Yan
1Department of Medicinal Chemistry, School of Pharmacy, Fujian Medical University, Fuzhou, Fujian 350004, People's Republic of China.
Abstract:
The title coordination polymer, [CdBr(2)(C(8)H(8)N(4))(2)](n), arose from a layer-separated diffusion synthesis at room temperature. The title compound is isotypic with the I and Cl analogues. The Cd atom, located on an inversion center, is coordinated by two bromide ions and four N atoms (two from triazole rings and two from pyridyl rings) in a distorted trans-CdBr(2)N(4) octa-hedral arrangement. The bridging 1-(4-pyridyl-meth-yl)-1H-1,2,4-triazole ligands are twisted [dihedral angle between the triazole and pyridine rings = 72.56 (13)°], affording a two-dimensional 4(4) sheet structure in the crystal.
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