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(E)-Benzaldehyde (2,4,6-trichloro-phen-yl)hydrazone.

Yan-Lan Huang¹, Deng-Feng Li, Jian Sun

¹College of Chemical Engineering and Materials Science, Zhejiang University of Technology, People's Republic of China.

Acta Crystallographica. Section E, Structure Reports Online

|April 28, 2011

Summary

This summary is machine-generated.

This study synthesized a novel compound, C(13)H(9)Cl(3)N(2), via condensation. The molecule exhibits an E configuration and forms supramolecular chains through hydrogen bonding and pi-pi stacking in its crystal structure.

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Area of Science:

Organic Chemistry
Crystallography
Supramolecular Chemistry

Background:

Condensation reactions are fundamental in organic synthesis.
Understanding molecular configurations and crystal packing is crucial for predicting material properties.
Supramolecular chemistry explores non-covalent interactions that dictate material architecture.

Purpose of the Study:

To synthesize and characterize a novel compound derived from benzaldehyde and 2,4,6-trichlorophenylhydrazine.
To elucidate the molecular geometry, including configuration and dihedral angles.
To investigate the intermolecular interactions and crystal packing of the synthesized compound.

Main Methods:

Condensation reaction between benzaldehyde and 2,4,6-trichlorophenylhydrazine.
X-ray crystallography for determining molecular structure and crystal packing.
Analysis of hydrogen bonding and π-π stacking interactions.

Main Results:

Successful synthesis of the title compound C(13)H(9)Cl(3)N(2).
The molecule adopts an E configuration with a dihedral angle of 42.58° between the phenyl and trichlorophenyl rings.
Supramolecular chains are formed along the c axis via N-H⋯N hydrogen bonds.
π-π stacking interactions were observed between trichlorophenyl rings with specific distances.

Conclusions:

The study successfully synthesized and characterized a new organic compound.
The crystal structure reveals specific intermolecular interactions (hydrogen bonding and π-π stacking) that govern its self-assembly.
The findings contribute to the understanding of structure-property relationships in related organic molecules.