Calcium in the oxygen-evolving complex: structural and mechanistic role determined by X-ray spectroscopy

Vittal K Yachandra1, Junko Yano

  • 1Physical Biosciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA. VKYachandra@lbl.gov

Summary

Calcium (Ca) is crucial for the photosynthetic water-oxidation reaction. X-ray spectroscopy reveals a MnCa structure, highlighting Ca's essential role in the Mn(4)Ca catalytic center's mechanism.

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