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Induction of Microstreaming by Nonspherical Bubble Oscillations in an Acoustic Levitation System
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Communication: Bubbles, crystals, and laser-induced nucleation.

Brandon C Knott1, Jerry L LaRue, Alec M Wodtke

  • 1Department of Chemical Engineering, University of California, Santa Barbara, California 93106-5080, USA.

The Journal of Chemical Physics
|May 10, 2011
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Intense laser pulses can trigger crystal formation by first creating bubbles in solutions. This laser-induced bubble nucleation also occurs in carbonated water and can even happen without lasers, suggesting a link between bubble and crystal nucleation.

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Area of Science:

  • Physical Chemistry
  • Materials Science
  • Chemical Physics

Background:

  • Previous research linked intense laser pulses to accelerated crystal nucleation, primarily for ordered or high dielectric phases.
  • Existing mechanisms for laser-induced nucleation were limited to specific material properties.

Purpose of the Study:

  • To investigate laser-induced nucleation in systems beyond ordered or high dielectric phases.
  • To explore the role of bubble formation in laser-induced nucleation processes.
  • To determine if bubble nucleation can induce crystal nucleation independently of lasers.

Main Methods:

  • Irradiation of transparent solutions with short, intense laser pulses (visible and infrared).
  • Observation of bubble nucleation in carbonated water under laser treatment.
  • Investigation of crystal nucleation in argon and glycine cosupersaturated water, with and without laser induction, focusing on bubble dynamics.

Main Results:

  • Short intense laser pulses were shown to induce carbon dioxide (CO(2)) bubble nucleation in carbonated water.
  • In argon and glycine cosupersaturated water, escaping argon bubbles were observed to induce crystal nucleation spontaneously, without laser intervention.
  • A potential connection between laser-induced bubble nucleation and subsequent crystal nucleation was identified.

Conclusions:

  • Laser-induced bubble nucleation is a viable mechanism for initiating nucleation processes, extending beyond previously studied phases.
  • Bubble nucleation, whether induced by lasers or occurring naturally, can act as a trigger for crystal nucleation.
  • These findings suggest a unified mechanistic link between bubble formation and crystal nucleation in supersaturated solutions.