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Free Volume and Swelling in Thin Films of Poly(N-isopropylacrylamide) End-Capped with n-Butyltrithiocarbonate

S Harms1, K Rätzke, F Faupel

  • 1Institute for Materials Sience - Multicomponent Materials, Christian-Albrechts-University at Kiel, Kaiserstraße 2, 24143 Kiel, Germany.

Macromolecular Rapid Communications
|May 14, 2011
PubMed

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Molecular Weight of Step-Growth Polymers01:08

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Step growth polymerization involves bi or multifunctional monomers. Bifunctional monomers react to form linear step growth polymers, whereas multifunctional monomers react to form non-linear or branched polymers.
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
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