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Related Experiment Video

Updated: Jun 2, 2026

Gyroid Nickel Nanostructures from Diblock Copolymer Supramolecules
08:40

Gyroid Nickel Nanostructures from Diblock Copolymer Supramolecules

Published on: April 28, 2014

Block copolymer directed nanoporous metal thin films.

Hitesh Arora1, Zihui Li, Hiroaki Sai

  • 1Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853, USA; School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, New York 14853, USA; Current address: Intel Corporation, Chandler, Arizona 85226, USA.

Macromolecular Rapid Communications
|May 14, 2011
PubMed
Summary

Researchers developed a new method to create nanostructured metal thin films with high nanoparticle content. This technique uses spin coating and plasma cleaning, offering potential for catalysis and energy applications.

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Surface Chemistry

Background:

  • Porous metal thin films are crucial for catalysis, electrical contacts, plasmonics, and energy applications.
  • Creating high surface area nanostructured metal films is challenging due to metals' high surface energy.

Purpose of the Study:

  • To demonstrate a novel method for fabricating nanostructured metal nanoparticle hybrid thin films.
  • To achieve high nanoparticle loadings in these thin films.

Main Methods:

  • Utilizing spin coating with a mixture of block copolymer and ligand-stabilized platinum and palladium nanoparticles.
  • Employing plasma cleaning to remove organic components and form conductive metal films.

Main Results:

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Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization
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Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization

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Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
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Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles

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Last Updated: Jun 2, 2026

Gyroid Nickel Nanostructures from Diblock Copolymer Supramolecules
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Gyroid Nickel Nanostructures from Diblock Copolymer Supramolecules

Published on: April 28, 2014

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization
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Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization

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Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
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Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles

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  • Successful fabrication of nanostructured metal thin films with high nanoparticle loadings.
  • The resulting films are conductive.

    • Conclusions:

    • The described method provides direct access to nanostructured metal nanoparticle hybrid thin films.
    • This technique is potentially generalizable to other metals, nanoparticle mixtures, and intermetallics for various applications.