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Alternating Poly(Pt-salphen)-(p-phenyleneethynylene) as Phosphorescent Conjugated Linear-Rod and Coilable Sensory
Shenmei Sun1, Wah-Leung Tong, Michael C W Chan
1Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China.
Abstract:
Phosphorescent conjugated polymers consisting of alternating p-phenylene-ethynylene and 'para-' or 'meta-type' Pt(II)-salphen luminophore units have been synthesized. Side-arms bearing different substituents (n-alkoxy and acetylated-sugar) have afforded contrasting emission properties that are attributed to the polymer conformation, extent of π-stacking interactions and differences in chemical structure. Intriguing selectivity in luminescent sensing of metal ions has been observed.
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