Pd-nanoparticle-decorated ZnO nanowires: ultraviolet photosensitivity and photoluminescence properties

ZnO nanowires (NWs) have been decorated with Pd nanoparticles of sizes less than 10 nm (Pd-ZnO NWs) via a chemical solution route. The microstructural characterizations have been done using field emission scanning electron and high-resolution transmission electron microscopes. The effects of attaching Pd nanoparticles to the walls of ZnO NWs have been investigated by studying the ultraviolet (UV) photosensitivity and photoluminescence (PL) properties. The surface-modified NWs show a UV photosensitivity more than double and a response seven times faster compared to the bare NWs. The photocarrier relaxation under the steady UV illumination condition is quite different in Pd-ZnO NWs. The higher and faster photosensitivity has been explained on the basis of photocarrier transfer from the conduction band of ZnO to the Fermi level of Pd and subsequent electron trapping by the adsorbed O(2) molecules on the NWs' surface, which have been presented through a proposed model. The PL spectrum of Pd-ZnO NWs shows that the intensities of the band-edge and defect-related emissions decrease and increase, respectively, due to Pd anchoring, the effect being pronounced as the density of Pd nanoparticles increases.