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Updated: Jun 1, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
{4-[(Diphenyl-phosphino)methyl-amino]pyridinium-κP}bis-(nitrato-κO)silver(I)
Jing Shang1, Liu-Cheng Gui, Qing-Ling Ni
1School of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004, People's Republic of China.
Abstract:
In the title mononuclear complex, [Ag(C(18)H(18)N(2)P)(NO(3))(2)], the metal centre is coordinated in a slightly distorted trigonal-planar geometry by the P atom of the phosphine ligand and the O atoms of the two monodentate nitrate anions. In the crystal structure, complex mol-ecules are connected by inter-molecular N-H⋯O hydrogen bonds, forming chains running parallel to the b axis.
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