Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Video

Updated: Jun 1, 2026

Genetic Incorporation of Biosynthesized L-dihydroxyphenylalanine (DOPA) and Its Application to Protein Conjugation
10:24

Genetic Incorporation of Biosynthesized L-dihydroxyphenylalanine (DOPA) and Its Application to Protein Conjugation

Published on: August 24, 2018

dl-Asparaginium perchlorate.

Fatiha Guenifa, Lamia Bendjeddou, Aouatef Cherouana

    Acta Crystallographica. Section E, Structure Reports Online
    |May 18, 2011
    PubMed
    Summary
    This summary is machine-generated.

    Related Concept Videos

    You might also read

    Related Articles

    Articles linked to this work by shared authors, journal, and citation graph.

    Sort by
    Same author

    Synthesis and structure of 4,5-diphenyl-1<i>H</i>-imidazol-3-ium thio-cyanate.

    Acta crystallographica. Section E, Crystallographic communications·2026
    Same author

    <i>fac</i>-Tris(dimethyl sulfoxide-κ<i>O</i>)tris-(thio-cyanato-κ<i>N</i>)iron(III).

    IUCrData·2026
    Same author

    Crystal structure and Hirshfeld surface analysis of the zero-dimensional hybrid perovskite 1,4-diazoniabicyclo[2.2.2]octane hexabromidostannate(IV).

    Acta crystallographica. Section C, Structural chemistry·2026
    Same author

    2-Oxo-2<i>H</i>-chromen-7-yl 4-ethyl-benzoate.

    IUCrData·2026
    Same author

    2-Oxo-2<i>H</i>-chromen-7-yl <i>tert</i>-butyl-acetate.

    IUCrData·2025
    Same author

    Synthesis and structure of 2-oxo-2<i>H</i>-chromen-4-yl 4-bromo-benzoate: work carried out as part of the CNRS AFRAMED project.

    Acta crystallographica. Section E, Crystallographic communications·2025

    The crystal structure reveals l- and d-asparginium cations alongside perchlorate anions, forming a 3D network via extensive hydrogen bonding. This arrangement influences molecular assembly and crystal packing in the title compound.

    Area of Science:

    • Crystallography
    • Solid-state chemistry
    • Structural analysis

    Background:

    • Asparagine is a crucial amino acid with implications in biological systems.
    • Understanding the solid-state structure of amino acid derivatives provides insights into intermolecular interactions.
    • Perchlorate salts are common counterions used in crystallographic studies.

    Purpose of the Study:

    • To elucidate the crystal structure of the title compound, C(4)H(9)N(2)O(3) (+)·ClO(4) (-).
    • To investigate the hydrogen bonding network and molecular assembly in the crystal lattice.
    • To characterize the enantiomeric forms of asparginium cations present in the structure.

    Main Methods:

    • Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.

    More Related Videos

    Antimicrobial Peptides Produced by Selective Pressure Incorporation of Non-canonical Amino Acids
    11:56

    Antimicrobial Peptides Produced by Selective Pressure Incorporation of Non-canonical Amino Acids

    Published on: May 4, 2018

    Related Experiment Videos

    Last Updated: Jun 1, 2026

    Genetic Incorporation of Biosynthesized L-dihydroxyphenylalanine (DOPA) and Its Application to Protein Conjugation
    10:24

    Genetic Incorporation of Biosynthesized L-dihydroxyphenylalanine (DOPA) and Its Application to Protein Conjugation

    Published on: August 24, 2018

    Antimicrobial Peptides Produced by Selective Pressure Incorporation of Non-canonical Amino Acids
    11:56

    Antimicrobial Peptides Produced by Selective Pressure Incorporation of Non-canonical Amino Acids

    Published on: May 4, 2018

  • Analysis of hydrogen bonding interactions (N-H⋯O, O-H⋯O, C-H⋯O) was performed.
  • Graph-set theory was utilized to describe the hydrogen bonding motifs within the asparginium layers.

    • Main Results:

    • The crystal structure contains both l- and d-asparginium cations, enantiomers related by glide planes.
    • A 1:1 ratio of asparginium cations to perchlorate anions was observed.
    • Molecules assemble into double layers parallel to the (100) plane through various hydrogen bonds.
    • Specific hydrogen bond motifs, R(2)(2)(8) and R(4)(3)(18), were identified within the asparginium layers.
    • A three-dimensional network is formed through interactions between cations and anions.

    Conclusions:

    • The crystal structure provides a detailed understanding of how asparginium cations and perchlorate anions interact.
    • The identified hydrogen bonding patterns dictate the supramolecular architecture and packing in the solid state.
    • The presence of enantiomeric cations highlights the potential for chiral recognition or packing effects in this system.