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Updated: Jun 1, 2026

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
Published on: August 7, 2018
catena-Poly[[[aqua-(2,2'-bipyridine)manganese(II)]-μ-5-methoxy-iso-phthalato-κO,O':O''] monohydrate]
1Department of Applied Engineering, Zhejiang Economic and Trade Polytechnic, 310018 Hangzhou, People's Republic of China.
Abstract:
In the title compound, {[Mn(C(8)H(4)O(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Mn(II) centre is octa-hedrally coordinated by three O atoms from two 5-methoxy-isophthalate (CH(3)O-ip) ligands, a fourth from a coordinated water mol-ecule and two N atoms from one chelating 2,2'-bipyridine (2,2-bipy) ligand. Each pair of adjacent Mn(II) atoms is bridged by a CH(3)O-ip ligand, forming a helical chain running along a crystallographic 2(1) axis in the c-axis direction. These chains are decorated with 2,2'-bipy ligands on alternating sides. O-H⋯O hydrogen bonding involving the water molecules stabilizes the crystal structure.
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