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Updated: Jun 1, 2026
06:31
Preparation of SNS Cobalt(II) Pincer Model Complexes of Liver Alcohol Dehydrogenase
Published on: March 19, 2020
(N,N-Diethyl-dithio-carbamato-κS,S')iodido(1,10-phenanthroline-κN,N')copper(II).
Summary
This study details the crystal structure of a novel copper(II) compound, revealing a distorted tetragonal coordination influenced by N-heterocycle and dithio-carbamate ligands. The structure features an iodine atom completing the coordination sphere.
Area of Science:
- Coordination Chemistry
- Crystallography
Background:
- Copper(II) complexes are vital in catalysis and materials science.
- Understanding coordination geometries provides insights into reactivity.
Purpose of the Study:
- To elucidate the coordination environment and crystal structure of a novel copper(II) complex.
- To characterize the bonding interactions within the complex.
Main Methods:
- Single-crystal X-ray diffraction analysis was employed.
- The crystal structure was solved and refined.
Main Results:
- The copper(II) atom exhibits a distorted tetragonal coordination geometry.
- Chelation by N-heterocycle and dithio-carbamate ligands was observed.
- An iodine atom occupies the apical position, completing the coordination sphere.
- Disordered ethyl group observed with specific site occupancies.
Conclusions:
- The study provides a detailed structural characterization of the copper(II) complex.
- The findings contribute to the understanding of copper coordination chemistry.
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
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